Synthesis of zinc trifluoromethanesulfonate

Preparation of zinc trifluoromethanesulfonate

The detailed synthesis procedure with the pictures is provided by  http://forum.lambdasyn.org/index.php/topic,2368.0.html

65 mg of zinc powder is suspended in 30 ml of acetonitrile and 300 mg of trifluoromethanesulfonic was dropped. The immediate evolution of hydrogen gas appears. The reaction mixture is placed in the conventional ultrasonic bath and ultrasonicated until the complete disappearance of the metal by maintaining the temperature at 0° C. Thereafter, the solution is filtered,  the solvent was removed by evaporation under vacuum and dried in a vacuum desiccator for few hours. The yield almost quantitative as zinc trifluoromethanesulfonate with 1.6 molecules of acetonitrile (Zn(OTf)· 1.6 CH3CN).

Eur J. Org Chem 901-904, 2012

IUPAC Name

zinc;trifluoromethanesulfonate

InChI

InChI=1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI Key

CITILBVTAYEWKR-UHFFFAOYSA-L

Canonical SMILES

C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Zn+2]

MeSH Synonyms

AgOTf cpd, Al(OTf)3, aluminum triflate, As(otf)2, cerium triflate, Cu(OTf)2, cupric trifluoromethanesulfonate, Eu(OTf)3, In(OTf)3, indium triflate, mercury(II) trifluoromethanesulfonate, samarium triflate, silver triflate, silver trifluoromethanesulfonate, TFMSA cpd, triflic acid, trifluoromethanesulfonate, trifluoromethanesulfonic acid, trifluoromethanesulfonic acid, aluminum salt, trifluoromethanesulfonic acid, barium salt, trifluoromethanesulfonic acid, cerium (+3) salt, trifluoromethanesulfonic acid, cupric salt, trifluoromethanesulfonic acid, indium salt, trifluoromethanesulfonic acid, lanthanum (+3) salt, trifluoromethanesulfonic acid, lithium salt, trifluoromethanesulfonic acid, samarium salt, trifluoromethanesulfonic acid, silver (+1) salt, trifluoromethanesulfonic acid, zinc salt, zinc triflate

Depositor-Supplied Synonyms

Zinc trifluoromethanesulfonate, 54010-75-2, Zinc(II) Trifluoromethanesulfonate, Zinc triflate, Zinc trifluoromethanesulphonate, Zinc(II) Triflate, zinc(2+) ion ditriflate, Trifluoromethanesulfonic acid zinc salt, ZINC(II) TRIFLUOROMETHANESULPHONATE, Methanesulfonic acid, trifluoro-, zinc salt, Trifluoromethanesulfonic Acid Zinc(II) Salt, Methanesulfonic acid, 1,1,1-trifluoro-, zinc salt (2:1), 1493-13-6 (Parent), zinc (II) triflate, 2CHF3O3S.Zn, ACMC-209lc6, AC1L2X9R, ZN(OTF)2, KSC491A8J, SCHEMBL165265, zinc, ion (zn2+) ditriflate, 290068_ALDRICH, 96517_FLUKA, CTK3J1084, CITILBVTAYEWKR-UHFFFAOYSA-L, MolPort-001-777-862, zinc (II) trifluoromethanesulfonate, ZINC TRIFLUOROMETHYLSULFONATE, ZINCTRIFLUOROMETHANESULFONATE, ACT09824, zinc tris(fluoranyl)methanesulfonate, EINECS 258-922-6, ANW-31924, PC8034, AKOS005258662, LS41181, RTR-019094, SC10875, TRA0049680, BIS(TRIFLUOROMETHANESULFONATO)ZINC, zinc(2+) ion ditrifluoromethanesulfonate, AK158308, AN-40692, OR024728, OR281136, SC-20951, AB1011131, DB-009916, ST24050376, X3710, K-9763, A829906, I14-3393, 3B3-084101, Trifluoromethanesulfonic acid zinc(II) salt; zinc(II) triflate, 919781-74-1

Removed Synonyms

CID104671, T1294

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