Preparation of bromoacetone
The reaction mixture is gently heated to 70° C. Slowly 91 g elemental bromine are added from the dropping-funnel. To initialize the reaction during the addition of bromine the flask being exposed to the direct light from a 750-watt lamp. At the end of the reaction when the liquid is colorized 60 ml of water are added. The flask is cooled and excess of hydrobromic acid is neutralized with the saturated solution of sodium carbonate. The final reaction product forms as oil which is separated, dried and distilled in vacuum. The product is a colorless liquid with a pungent odor and boiling point 136° C.
The war gases chemistry and analysis, by M. Sartory,, 150, 1939.
BROMOACETONE, 1-Bromo-2-propanone, Monobromoacetone, 1-bromopropan-2-one, Martonite, 598-31-2, Acetonyl bromide, 1-Bromoacetone, 2-Propanone, 1-bromo-, Bromo-2-propanone, Bromomethyl methyl ketone, B-Stoff, Acetylmethyl bromide, Acetyl methyl bromide, 2-Propanone, bromo-, bromopropanone, 1-bromo-propan-2-one, bromo acetone, RCRA waste number P017, BA (tear gas), .alpha.-Bromoacetone, RCRA waste no. P017, HSDB 315, CHEMBL1085947, CHEBI:51845, VQFAIAKCILWQPZ-UHFFFAOYSA-N, EINECS 209-928-2, UN1569, UN 1569, BRN 0741886, alpha-Bromoacetone, bromo 2-propanone, Bromo-propan-2-one, .alpha.-Bromopropanone, CH3COCH2Br, PubChem24199, 1-bromanylpropan-2-one, AC1L1XYU, ACMC-1AO0E, UNII-3O8L0EWR5Q, 3O8L0EWR5Q, SCHEMBL56383, KSC492A6B, AMOT0243, GTPL6293, CTK3J2060, 2-Propanone, 1-bromo- (9CI), MolPort-001-779-899, Bromoacetone [UN1569] [Poison], ANW-41529, Bromoacetone [UN1569] [Poison], AKOS000210999, AM85840, AK-83409, AN-46274, BC253377, CJ-07518, CJ-31883, KB-64996, SC-20936, AB0052771, DB-005702, LS-122773, RT-000196, B0642, FT-0080467, FT-0600316, 20636-EP2308839A1, 20636-EP2314585A1, A832491, InChI=1/C3H5BrO/c1-3(5)2-4/h2H2,1H, S14-1099, 3B3-051477
|A-Bromoacetone, CID11715, RW1394, 4-01-00-03223 (Beilstein Handbook Reference), BA