Synthesis of pentyl sulfide

Preparation of pentyl sulfide

Preparation of pentyl sulfide

Preparation of pentyl sulfide

100 g of n-amyl bromide are added slowly to a solution of 198.8 g. of sodium sulfide nonahydrate in 500 ml. of ethanol. The mixture is heated to reflux for 2 hours, and after it is cooled to room temperature the precipitated oil is removed. The remaining liquid is poured into 750 ml. of 25% aqueous sodium chloride solution, and the precipitated oil is separated. The combined oil fractions are dried over anhydrous sodium sulfate and distilled twice through a 36-cm. Hempel fractionating column filled with glass beads. The yield based on bromide is 74 %, and the product boils at 227°.

J. Am. Chem. Soc., 61, 84 (1939).

IUPAC Name

1-pentylsulfanylpentane

InChI

InChI=1S/C10H22S/c1-3-5-7-9-11-10-8-6-4-2/h3-10H2,1-2H3

InChI Key

JOZDADPMWLVEJK-UHFFFAOYSA-N

Canonical SMILES

CCCCCSCCCCC

Depositor-Supplied Synonyms

Pentyl sulfide, Diamyl sulfide, 872-10-6, Amyl sulfide, Pentane, 1,1′-thiobis-, n-Amyl sulfide, Dipentyl sulfide, 1-(Pentylsulfanyl)pentane, Dipentyl sulphide, Di-n-pentyl sulfide, 1-pentylsulfanylpentane, pentylthiopentane, SBB060112, Diamyl sulphide, 6-Thiaundecane, di-n-Amyl sulfide, Di-n-pentylsulfide, N-AMYLSULFIDE, 1,1′-Thiobispentane, ACMC-209qit, AC1Q2WPD, DSSTox_CID_22266, DSSTox_RID_79982, DSSTox_GSID_42266, 1-(Pentylsulfanyl)pentane #, SCHEMBL226036, UNII-61XJN3644R, AC1L21M0, CHEMBL3184537, CTK3J2259, JOZDADPMWLVEJK-UHFFFAOYSA-, JOZDADPMWLVEJK-UHFFFAOYSA-N, MolPort-001-817-585, 61XJN3644R, ZINC2040263, EINECS 212-820-8, Tox21_301954, 5783AF, ANW-38643, ZINC02040263, AKOS006228806, MCULE-3839664161, RTR-027299, NCGC00255753-01, CAS-872-10-6, CJ-32359, LP001974, AI3-01368, DB-056982, TR-027299, A0673, FT-0625196, ST50410294, 3B3-021232, InChI=1/C10H22S/c1-3-5-7-9-11-10-8-6-4-2/h3-10H2,1-2H3

Removed Synonyms

CID13382

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