Synthesis of N-nitroso-N-methylaniline

Preparation of N-nitroso-N-methylaniline

Preparation of N-nitroso-N-methylaniline

Preparation of N-nitroso-N-methylaniline

10 g methylaniline dissolved in 15 ml conc. hydrochloric acid and 40 g ice are treated with 7 g sodium nitrite in 25 ml water. N-Nitroso-N-methylaniline separates as a yellow oil, which solidifies on cooling (m.p. 12°-15° C)

Systematic organic chemistry, by W. M. Cumming, 285, 1937.

IUPAC Name

N-methyl-N-phenylnitrous amide

InChI

InChI=1S/C7H8N2O/c1-9(8-10)7-5-3-2-4-6-7/h2-6H,1H3

InChI Key

MAXCWSIJKVASQC-UHFFFAOYSA-N

Canonical SMILES

CN(C1=CC=CC=C1)N=O

MeSH Synonyms

methylphenylnitrosamine, N-methyl-N-nitrosoaniline, N-methyl-N-nitrosobenzenamine, N-nitroso-N-methylaniline, N-nitrosomethylaniline, N-nitrosomethylphenylamine, phenylmethylnitrosamine

Depositor-Supplied Synonyms

N-Nitroso-N-methylaniline, N-Methyl-N-nitrosoaniline, Nitrosomethylaniline, 614-00-6, Phenylmethylnitrosamine, Methylphenylnitrosamine, Benzenamine, N-methyl-N-nitroso-, N-Nitrosomethylphenylamine, N-Methyl-N-phenylnitrosamine, Aniline, N-methyl-N-nitroso-, N-methyl-N-phenylnitrous amide, N-Methyl-N-nitrosaniline, Methylnitrosoaniline, N-Methyl-N-phenylnitrosoamine, NSC 137, N-METHYL-N-NITROSOBENZENAMINE, Methylnitroso phenylamine, CCRIS 400, HSDB 5072, EINECS 210-366-5, BRN 1841401, AI3-01373, DSSTox_CID_1053, DSSTox_RID_75921, DSSTox_GSID_21053, CAS-614-00-6, Methylphenylnitrosoamine, Nitroso-N-methylaniline, ACMC-209mse, Methyl-phenyl-nitrosamine, AC1L1YIU, AC1Q3XJ7, WLN: ONN1&R, UNII-9SM68I29WQ, SCHEMBL301282, 9SM68I29WQ, CHEMBL266169, NSC137, NSC-137, MAXCWSIJKVASQC-UHFFFAOYSA-N, MolPort-001-779-991, 1-Methyl-2-oxo-1-phenylhydrazine, ZINC4352943, Tox21_201508, Tox21_302747, ANW-33804, ZINC04352943, 1-Methyl-2-oxo-1-phenylhydrazine #, AKOS008996592, LS-7613, TRA0067113, NCGC00249056-01, NCGC00256430-01, NCGC00259059-01, AJ-50840, AK136017, KB-58701, OR026348, OR297651, DB-053868, TC-122549, FT-0632561, N0264, EN300-18654, W-2902, S01-0388, N-Methyl-N-nitrosoaniline, N-Nitrosomethylphenylamine, 3B3-050780, InChI=1/C7H8N2O/c1-9(8-10)7-5-3-2-4-6-7/h2-6H,1H

Removed Synonyms

N-nitrosomethylaniline, CID11957, 4-16-00-00864 (Beilstein Handbook Reference), C014102, NMA

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