Synthesis of hydroxylamine phosphate

Preparation of hydroxylamine phosphate

Preparation of hydroxylamine phosphate

Preparation of hydroxylamine phosphate

21 g of hydroxylammonium chloride are dissolved in 20ml of water at 40°C and constantly stirred while 12g of 85% phosphoric acid are added in one portion. An ice-cold solution of 12g of sodium hydroxide in 40ml of water is rapidly added dropwise from a separatory funnel while stirring is maintained. To avoid decomposition during the addition of the alkali, the temperature should not rise above 70°C; if necessary, the reaction mixture should be temporarily cooled in cold water. When all of the sodium hydroxide has been added, the crystalline slurry is cooled to 15°C, suction-filtered, and washed carefully three times with 10-ml portions of ice water. The obtained hydroxylamine phosphate is dried in vacuo yielding 16-18 g of final product.

Inorganic laboratory preparations, by G. G. Schlessinger, 77-78, 1962

IUPAC Name

hydroxylamine;phosphoric acid

InChI

InChI=1S/3H3NO.H3O4P/c3*1-2;1-5(2,3)4/h3*2H,1H2;(H3,1,2,3,4)

InChI Key

XBUFCZMOAHHGMX-UHFFFAOYSA-N

Canonical SMILES

NO.NO.NO.OP(=O)(O)O

Depositor-Supplied Synonyms

Hydroxylammonium phosphate, Hydroxylamine phosphate salt (3:1), HYDROXYLAMINEPHOSPHATE, 55485_ALDRICH, 342351_ALDRICH, 55485_FLUKA

Removed Synonyms

Hydroxylamine phosphate, IUPAC: Hydroxylamine; Phosphoric Acid, CID11252585, 20845-01-6

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