Synthesis of hydrobenzamide

Preparation of hydrobenzamide

Preparation of hydrobenzamide

Preparation of hydrobenzamide

5 ml of benzaldehyde and 25 ml conc. ammonium hydroxide solution are placed in a stoppered flask and allowed to stand for 2 days. Crystals of hydrobenzamide separate, which are filtered off, washed with water, and recrystallised from alcohol. Yield  90% theoretical (4.2 gms.). m.p. 110° C; insoluble in water, easily soluble in alcohol.

Systematic organic chemistry, by W. M. Cumming, 307, 1937.

IUPAC Name

(E)-N-[[(E)-benzylideneamino]-phenylmethyl]-1-phenylmethanimine

InChI

InChI=1S/C21H18N2/c1-4-10-18(11-5-1)16-22-21(20-14-8-3-9-15-20)23-17-19-12-6-2-7-13-19/h1-17,21H/b22-16+,23-17+

InChI Key

VUYRFIIFTJICNA-LKNRODPVSA-N

Canonical SMILES

C1=CC=C(C=C1)C=NC(C2=CC=CC=C2)N=CC3=CC=CC=C3

Isomeric SMILES

C1=CC=C(C=C1)/C=N/C(/N=C/C2=CC=CC=C2)C3=CC=CC=C3

Depositor-Supplied Synonyms

Hydrobenzamide, N,.alpha.-diamine, Methanediamine, 1-phenyl-N,N’-bis(phenylmethylene)-, n,n’-dibenzylidene-1-phenylmethanediamine, ST001504, N,N’-Dibenzylidenetoluene-alpha,alpha-diamine, Toluene-.alpha.,.alpha.-diamine, N,N’-dibenzylidene-, Toluene-.alpha., N,N’-dibenzylidene-, Methanediamine,N’-bis(phenylmethylene)-, 92-29-5, NSC1005, AC1Q4TBH, 167649_ALDRICH, SCHEMBL14163512, MolPort-001-783-852, VUYRFIIFTJICNA-LKNRODPVSA-N, HMS1534K08, NSC 1005, NSC-1005, EINECS 202-144-1, AR-1K1783, NSC122123, STK293187, AKOS001709712, MCULE-1132426291, NSC-122123, .alpha.,.alpha.-Bis(benzylidenimino)toluene, FT-0627121, AB01221213-03, N,N’-Dibenzylidenetoluene-.alpha.,.alpha.-diamine, BRD-K74234633-001-01-4, Phenyl-N,N-bis[(E)-phenylmethylidene]methanediamine #, (1E,4E)-1,3,5-triphenyl-2,4-diazapenta-1,4-diene, 1-phenyl-N,N’-bis[(E)-phenylmethylidene]methanediamine, Toluene-alpha,alpha-diamine, N,N’-dibenzylidene- (8CI), A0601/0027821, A0630/0029217, N,N inverted exclamation marka-Dibenzylidenetoluene-|A,|A-diamine, 77008-39-0

Removed Synonyms

CID9566477, 6974-01-2

Share This

Leave a Reply

Your email address will not be published. Required fields are marked *