Synthesis of ethyl 3,5-dinitrobenzoate

Preparation of ethyl 3,5-dinitrobenzoate

Preparation of ethyl 3,5-dinitrobenzoate

Preparation of ethyl 3,5-dinitrobenzoate

5 g of 3,5-dinitrobenzoic acid and 5 g of phosphorus pentachloride are gently warmed and the mixture allowed to cool. The solid dinitrobenzoyl chloride is separated from the phosphorus oxychloride by pressing on a porous plate. The crude chloride is then treated with 5 ml of ethyl alcohol, under reflux, and warmed to about 80° C for 10 minutes. The product is crystallised from 60% alcohol. m.p. 92° C.

Systematic organic chemistry, by W. M. Cumming, 128, 1937.

IUPAC Name

ethyl 3,5-dinitrobenzoate

InChI

InChI=1S/C9H8N2O6/c1-2-17-9(12)6-3-7(10(13)14)5-8(4-6)11(15)16/h3-5H,2H2,1H3

InChI Key

IBQREHJPMPCXQA-UHFFFAOYSA-N

Canonical SMILES

CCOC(=O)C1=CC(=CC(=C1)[N+](=O)[O-])[N+](=O)[O-]

Depositor-Supplied Synonyms

Ethyl 3,5-dinitrobenzoate, 618-71-3, IBQREHJPMPCXQA-UHFFFAOYSA-N, Benzoic acid, 3,5-dinitro-, ethyl ester, ST50186542, NSC32741, AC1L2BGS, ACMC-20al01, AC1Q5AI5, 301337_ALDRICH, SCHEMBL1114367, CTK5B3938, MolPort-003-791-948, ZINC1665097, 3,5-dinitrobenzoic acid ethyl ester, EINECS 210-559-4, AR-1I8716, NSC-32741, ZINC01665097, 3,5-dinitro-benzoic acid ethyl ester, AKOS002271179, AKOS015889568, Benzoic acid,5-dinitro-, ethyl ester, MCULE-4467837885, Benzoic acid,3,5-dinitro-, ethyl ester, CJ-26917, OR025289, DB-054011, KB-201543, TC-166888, FT-0614717, TL80090805, I01-19860, 3B3-030090

Removed Synonyms

CID69255, 6304-93-4

Share This

Leave a Reply

Your email address will not be published. Required fields are marked *