Synthesis of bismuth triiodide (bismuth(III) iodide)

Preparation of bismuth triiodide

Preparation of bismuth triiodide (bismuth(III) iodide)

Preparation of bismuth triiodide (bismuth(III) iodide)

20 g iodine are mixed with 35 g finely powdered bismuth in a mortar, quickly poured into a short neck distillation flask fitted short air condenser. The reaction flask is slowly heated on the gas stove and when the reaction is finished the small quantity of excess iodine is removed by a current of dry carbon dioxide Then the temperature raised until the bismuth triiodide sublimes in form of very large crystals, similar in appearance to iodine. bismuth triiodide is additionally purified by re-sublimation, yielding gray-black solid.

Laboratory manual of inorganic preparations, by H. T. Vulte, 140-141, 1895

IUPAC Name

triiodobismuthane

InChI

InChI=1S/Bi.3HI/h;3*1H/q+3;;;/p-3

InChI Key

KOECRLKKXSXCPB-UHFFFAOYSA-K

Canonical SMILES

I[Bi](I)I

MeSH Synonyms

bismuth iodide, bismuth iodide (1:3)

Depositor-Supplied Synonyms

Bismuth iodide, Bismuth triiodide, Bismuth(III) iodide, triiodobismuthane, Bismuthine, triiodo-, 7787-64-6, Bismuth iodide (BiI3), triiodobismuthine, 12262-07-6, Triiodobismuth, Bismuth iodide, BiI3, Bismuth iodide (VAN), AC1L38VZ, AC1Q4P2H, KSC179G5D, 229474_ALDRICH, 341010_ALDRICH, 456837_ALDRICH, CTK0H9351, MolPort-003-928-203, EINECS 232-127-4, AR-1L7399, NSC103681, AKOS015902622, NSC 103681, NSC-103681, TRA0168676, AB1006875, TR-024923, I14-19750, Triiodobismuth; Bismuth iodide (VAN); Triiodobismuthane; Bismuth(+3) trihydride cation triiodide

Removed Synonyms

UNII-BGX9X3FOLL, CID111042, 82475-11-4

Share This

Leave a Reply

Your email address will not be published. Required fields are marked *