Synthesis of ammonium sulfide

Preparation of ammonium sulfide

By treating ammonium hydroxide with an excess of hydrogen sulfide ammonium hydrosulfide (NH4HS) forms, which with further treatment with the same quantity of ammonia yields ammonium sulfide:

Preparation of ammonium sulfide

Preparation of ammonium sulfide

Hydrogen sulfide is passed through 3 parts of concentrated ammonium hydroxide solution until no further absorption takes place. Then 2 parts of concentrated ammonium hydroxide solution is added in order to neutralize NH4HS. The rule, however, is to add only two-thirds of the quantity of solution of ammonium hydroxide, as it is better the preparation should contain a little ammonium hydrosulfide than that free ammonia should be present. Ammonium sulfide should be well protected from air and moisture.

Laboratory manual of inorganic preparations, by H. T. Vulte, 41-42, 1895

IUPAC Name

diazanium;sulfide

InChI

InChI=1S/2H3N.S/h2*1H3;/q;;-2/p+2

InChI Key

UYJXRRSPUVSSMN-UHFFFAOYSA-P

Canonical SMILES

[NH4+].[NH4+].[S-2]

MeSH Synonyms

ammonium sulfide, ammonium sulphide

Depositor-Supplied Synonyms

Diammonium sulfide, ammonium sulfide, 40-50% solution in water, diazanium sulfide, 2H0Q32TDFZ, A1952_SIGMA, W205303_ALDRICH, 11230_RIEDEL, 515809_ALDRICH, A1952_SIAL, AC1L199F, 515809_SIAL, BP-20355

Removed Synonyms

Ammonium sulphide, AMMONIUM SULFIDE, Ammonium sulfide solution, UNII-2H0Q32TDFZ, CID25519, 12124-99-1, 12135-76-1

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