Synthesis of acetyl bromide

Preparation of acetyl bromide

Preparation acetyl bromide from acetic acid and bromine

Preparation acetyl bromide from acetic acid and bromine

Preparation acetyl bromide from acetic acid and bromine

To a mixture of 150 grams glacial acetic acid and 10 grams red phosphorus, 400 grams of bromine are added slowly. The reaction mixture is boiled under reflux for an hour, and the acetyl bromide formed is distilled off by collecting fraction which boils at 76° C.

Preparation acetyl bromide from acetyl chloride and hydrogen bromide

Preparation acetyl bromide from acetyl chloride and hydrogen bromide

Preparation acetyl bromide from acetyl chloride and hydrogen bromide

Acetyl bromide may also be prepared by passing dry hydrogen bromide (3 moles) into acetyl chloride at room temperature and then distilling the solution.

Ber. Deut. Chem. Ges., 46, 1431, 1913

IUPAC Name

acetyl bromide

InChI

InChI=1S/C2H3BrO/c1-2(3)4/h1H3

InChI Key

FXXACINHVKSMDR-UHFFFAOYSA-N

Canonical SMILES

CC(=O)Br

MeSH Synonyms

acetyl bromide

Depositor-Supplied Synonyms

ACETYL BROMIDE, Ethanoyl bromide, 506-96-7, Acetylbromide, Acetic acid, bromide, CH3COBr, UNII-O18V5XYO0G, HSDB 663, FXXACINHVKSMDR-UHFFFAOYSA-N, EINECS 208-061-7, UN1716, BRN 1697546, bromomethyl ketone, AC1L1VAP, ACMC-1AXG3, O18V5XYO0G, SCHEMBL35161, KSC270I5R, 135968_ALDRICH, 00960_FLUKA, CTK1H0458, MolPort-001-757-409, LTBB002128, ANW-31101, AKOS009031561, NE10006, RP19498, RTR-018121, UN 1716, Acetyl bromide [UN1716] [Corrosive], Acetyl bromide [UN1716] [Corrosive], AN-45430, InChI=1/C2H3BrO/c1-2(3)4/h1H, LS-13936, DB-071242, KB-250612, TR-018121, A0080, FT-0621822, 4-02-00-00398 (Beilstein Handbook Reference), A828254, 3B4-0699, I14-6838

Removed Synonyms

CID10482

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