Synthesis of 2-chloroacrylonitrile

Preparation of 2-chloroacrylonitrile

Preparation of 2-chloroacrylonitrile

Preparation of 2-chloroacrylonitrile

2-Chloroacrylonitrile is obtained by removal of hydrogen chloride from 2,3-dichloropropionitrile by sodium acetate in methanol; it can be distilled at atmospheric pressure (b.p. 87-89°/736 mm) if a little hydroquinone is added to prevent polymerization.

Angew. Chem., 60, 311 (1948).

IUPAC Name

2-chloroprop-2-enenitrile

InChI

InChI=1S/C3H2ClN/c1-3(4)2-5/h1H2

InChI Key

OYUNTGBISCIYPW-UHFFFAOYSA-N

Canonical SMILES

C=C(C#N)Cl

MeSH Synonyms

2-chloroacrylonitrile, alpha-chloroacrylonitrile

Depositor-Supplied Synonyms

2-Chloroacrylonitrile, 920-37-6, Chloroacrylonitrile, 2-Propenenitrile, 2-chloro-, Acrylonitrile, 2-chloro-, 2-chloroprop-2-enenitrile, 2-Chloro-2-propenenitrile, .alpha.-Chloroacrylonitrile, CCRIS 6869, OYUNTGBISCIYPW-UHFFFAOYSA-N, EINECS 213-055-2, NSC 511714, BRN 0773744, 2chloroacrylonitrile, chloro acrylonitrile, PubChem2144, 2-chloro-acrylonitrile, 2-Chloro acrylonitrile, 2-chloro-propenenitrile, PubChem15121, alpha-Chloroacrylonitrile, alpha-chloro-acrylonitrile, Alpha-chloro acrylonitrile, WLN: NCYGU1, Propenenitrile, 2-chloro-, UNII-FFJ1QHD154, AC1L2DK8, FFJ1QHD154, C22369_ALDRICH, KSC486S1B, 2-CHLORO-2-PROPENITRILE, CTK3I6910, MolPort-001-769-333, ACT02937, ZINC1603500, ANW-39789, KM3073, NSC511714, OR5754, ZINC01603500, AKOS009159505, NSC-511714, RP18484, RTR-031876, AN-47958, BC209246, BP-12653, CJ-25820, KB-22796, LS-14754, OR000204, OR150421, DB-005232, ST2409922, TR-031876, FT-0080076, InChI=1/C3H2ClN/c1-3(4)2-5/h1H, 90355-EP2301929A1, 90355-EP2301935A1, 90355-EP2305674A1, I14-0081, 3B3-003580

Removed Synonyms

2-Chlorocyanoethylene, CID70198, c0701, 4-02-00-01484 (Beilstein Handbook Reference)

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