Preparation of 2-chloro-2-methyl-3-nitrosobutane
Alternative Names: 2-chloro-2-methyl-3-nitrosobutane; 3-chloro-3-methyl-2-nitrosobutane; Butane, 2-chloro-2-methyl-3-nitroso-; 37557-67-8;
50 ml of ice-cold fuming hydrochloric acid are dropped during 1.5 hours into a stirred mixture of 30 g of 2-methyl-2-butene and 50 ml of pentyl nitrite kept below 0° C by ice-salt cooling. The mixture becomes blue at once and gradually solidifies to a mass of colorless crystals. The crystals are left in the cold for 30 min and then filtered off under suction and washed with ice-cold ethanol. The yield is 29 g and the m.p. 76° C.
J. Chem. Soc, 1956, 2588.
2-chloro-2-methyl-3-nitrosobutane, 3-chloro-3-methyl-2-nitrosobutane, Butane, 2-chloro-2-methyl-3-nitroso-, 37557-67-8, SCHEMBL526601, CTK1B5573, CHXRIVJFJWPWMR-UHFFFAOYSA-N, OR264299