Synthesis of 1-amino-2-methylnaphthalene

Preparation of 1-amino-2-methylnaphthalene

Preparation of 1-amino-2-methylnaphthalene

Preparation of 1-amino-2-methylnaphthalene

A mixture of 25 g. of 1-nitro-2-methylnaphthalene and 5 g. of Raney nickel catalyst in 75 ml. of ethanol is agitated under a hydrogen pressure of 1-3 atm. until the calculated amount of hydrogen has been absorbed. The catalyst is removed by filtration, and the filtrate is distilled to give 19.5 g. (93%) of the amine, b.p. 111-113°/0.3 mm., m.p. 31°.

J. Am. Chem. Soc., 64, 1476 (1942).

IUPAC Name

2-methylnaphthalen-1-amine

InChI

InChI=1S/C11H11N/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,12H2,1H3

InChI Key

JMBLSGAXSMOKPN-UHFFFAOYSA-N

Canonical SMILES

CC1=C(C2=CC=CC=C2C=C1)N

Depositor-Supplied Synonyms

1-Amino-2-methylnaphthalene, 2246-44-8, 2-methylnaphthalen-1-amine, 2-Methyl-1-naphthylamine, 2-Methyl-1-naphthalenamine, 2-Methyl-1-naftylamin, 1-NAPHTHYLAMINE, 2-METHYL-, BRN 2042530, 1-Naphthalenamine,2-methyl-, 2-Methyl-1-naftylamin [Czech], JMBLSGAXSMOKPN-UHFFFAOYSA-N, ST51041661, 2-methylnaphthylamine, ACMC-1CQGH, UNII-UEU388PI4W, AC1L28KF, UEU388PI4W, 67960_ALDRICH, SCHEMBL157730, 1-Naphthalenamine, 2-methyl-, 2-Methyl-1-naphthalenamine #, 67960_FLUKA, CTK3J0730, MolPort-000-151-137, ZINC2038746, 1343AB, ANW-24884, ZINC02038746, AKOS006221190, MCULE-9551017439, NE56294, RTR-010571, TRA0084357, VZ21118, AJ-33124, AK-81542, CJ-32171, LS-95738, OR026548, OR120125, OR125232, DB-045928, KB-108765, TR-010571, A0917, FT-0634164, 5P-039, A21834, 3-12-00-03102 (Beilstein Handbook Reference), I08-0498, 3B3-015795

Removed Synonyms

CID16733

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